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Is this an outdoor sign? Anyway, the edges will suck up paint but if you seal them first with a good primer (I prefer an oil based version) you should be just fine. It wouldn't be a bad idea to use the primer over the smooth surfaces as well.
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Only the machined edges require special attention. The factory surfaces take paint beautifully. If you dress the edges with Sealcoat it will dry in 20 minutes and you can then apply the primer.
Putting a waterbased paint over the machined edges will allow the fibers to expand and it will have the texture of 40 grit sandpaper.
If you want a very smooth finish on the machined edges then you should add filler to the surface before the shellac. I like to use Parks' grain filler (usually used for oak flooring) as it dries very quickly, sands easily and takes paint well.
Hand sand the machined surfaces. Use the grain filler like shoe polish and rub it into the pores with a rag. Wait 30 minutes to 2 hours for it to dry and then hand sand again. Then seal with Sealcoat and then prime and paint.
Plaster joint compound works too but dries slower and sands messier. I would suggest that MDF is an indoor product only (and not to be used in bathrooms or places with lots of moisture). MDO is designed for exterior applications.
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Thanks guys, this is an indoor sign for an office.
Grant
"GO BUCKEYES"